Material Safety Data Sheet

Iron Titrant

MSDS Name: Iron Titrant
 Synonyms: None
Company Identification:
              Robinson Consulting
             609 8^th ave
             South Sioux City, NE. 68776
For information, call: 402.494.8250  or email TFRemily@aol.com
Emergency Number: 402.494.8250
 

Hazard Symbols: T N
Risk Phrases: 46 49 52/53

EMERGENCY OVERVIEW

Appearance: orange. May cause allergic respiratory reaction. May cause allergic skin reaction. Warning! May cause cancer based on animal studies. Cancer hazard. May cause eye and skin irritation. May cause respiratory and digestive tract irritation.
Target Organs: None known.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract.
Chronic: May cause cancer according to animal studies.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

OSHA Vacated PELs: Water: No OSHA Vacated PELs are listed for this chemical. Potassium Dichromate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Physical State: Liquid
Appearance: orange
Odor: none reported
pH: Not available.
Vapor Pressure: 14 mm Hg
Vapor Density: 0.7
Evaporation Rate:>1 (ether=1)
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Alcohols, hydrazine, hydroxylamine, sulfuric acid, boron, acetone, silica gel, ethylene glycol, silicon, tungsten.
Hazardous Decomposition Products: Oxides of potassium, no data available, chromium dioxide.
Hazardous Polymerization: Has not been reported.

RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 7778-50-9: HX7680000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;<BR.

CAS# 7778-50-9:
Oral, mouse: LD50 = 190 mg/kg;
Oral, rat: LD50 = 25 mg/kg;
Skin, rabbit: LD50 = 14 mg/kg;<BR.

Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7778-50-9:
ACGIH: A1 - Confirmed Human Carcinogen (listed as Chromium (VI) compounds- water solubl
California: carcinogen; initial date 2/27/87 (listed as Chromium (VI) compounds).
NTP: Known carcinogen (listed as Chromium (VI) compounds).
OSHA: Select carcinogen (listed as Chromium (VI) compounds).
IARC: Group 3 carcinogen (listed as Chromium).
Epidemiology: Certain hexavalent chromium compounds have been demonstrate d to be carcinogenic on the basis of epidemiologic investi gations on workers and experimental studies in animals.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

No information available.

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

US FEDERAL

TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7778-50-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 7778-50-9: 6/12b
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 7778-50-9: final RQ = 10 pounds (4.54 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7778-50-9: chronic.
Section 313
This material contains Potassium Dichromate (listed as ** undefined **), 1 0%, (CAS# 7778-50-9) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7778-50-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7778-50-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 46 May cause heritable genetic damage.
R 49 May cause cancer by inhalation.
R 52/53 Harmful to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.

Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 53 Avoid exposure - obtain special instructions
before use.
S 60 This material and/or its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.

WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7778-50-9: 3
Canada
CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7778-50-9 is listed on Canada's DSL List. CAS# 7778-50-9 is listed on Canada's DSL List.

This product has a WHMIS classification of D2A, D1A.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7778-50-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7778-50-9 (listed as ** undefined **): OEL-ARAB Republic of Egypt
:TWA 0.05 mg/m3 OEL-AUSTRALIA:TWA 0.05 mg/m3 OEL-BELGIUM:TWA 0.5 mg/
m3 OEL-DENMARK:TWA 0.5 mg/m3 OEL-FINLAND:TWA 0.01 mg/m3 OEL-FRANCE:
TWA 0.5 mg/m3 OEL-JAPAN:TWA 0.5 mg/m3 OEL-THE NETHERLANDS:TWA 0.5 mg
/m3 OEL-THE PHILIPPINES:TWA 1 mg/m3 OEL-SWEDEN:TWA 0.5 mg/m3 OEL-UN
ITED KINGDOM:TWA 0.5 mg/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA c
heck ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

MSDS Creation Date: 6-1-02
Revision Date: 8-11-11
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Robinson Consulting be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Robinson Consulting has been advised of the possibility of such damages.