Material Safety Data Sheet

Zinc Titrant

EDTA Solution

MSDS Name: Zinc Titrant
Synonyms:
Company Identification:

    Robinson Consulting

609 8^th ave
South Sioux City, NE. 68776
For information, call: 402.494.8250  or email TFRemily@aol.com
Emergency Number: 402.494.8250
 

Hazard Symbols: XI
Risk Phrases: 36 52 53

EMERGENCY OVERVIEW

Appearance: Not available. Caution! May cause eye and skin irritation. May cause skin sensitization by skin contact. May cause eye and skin irritation. May cause respiratory and digestive tract irritation. May cause kidney damage. May cause allergic skin reaction. May cause reproductive and fetal effects.
Target Organs: Kidneys, bone marrow.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: May cause irritation of the digestive tract. Exposure may cause kidney injury, muscle cramps, bone-marrow depression, and a generalized allergic reaction.
Inhalation: May cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or chemical foam.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

OSHA Vacated PELs: Ethylenediaminetetraacetic acid (EDTA): No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Physical State: Liquid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases, copper, copper alloys, aluminum.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

RTECS#:
CAS# 60-00-4: AH4025000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 60-00-4:
Oral, mouse: LD50 = 30 mg/kg;<BR.

CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;<BR.

Carcinogenicity:
CAS# 60-00-4: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: Embryo or Fetus: Stunted fetus, oral-rat TDLo=7632mg/kg. Specific Developmental Abnormalities: Cardiovascular, Craniofacial, Musculoskeletal, Respiratory, and Urogenital, oral-rat TDLo=7632mg/kg.
Reproductive Effects: Fertility: Post-implantation mortality, oral-rat TDLo=7632mg/kg.
Neurotoxicity: No information available.
Mutagenicity: Cytogenetic Analysis: intraperitoneal-mouse 50mmol/L. DNA Inhibition: hamster fibroblast 500ug/L, rabbit kidney 250umol/L.
Other Studies: None.

Ecotoxicity: No data available. Catfish (tap water) 129ppm/96H.
Environmental: Biological Oxygen Demand (BOD): 1%, 5 days.
Physical: No information available.
Other: None.

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

US FEDERAL

TSCA
CAS# 60-00-4 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
CAS# 60-00-4: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 60-00-4 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 60-00-4 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36 Irritating to eyes.
R 52 Harmful to aquatic organisms.
R 53 May cause long-term adverse effects in the
aquatic environment.

Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.

WGK (Water Danger/Protection)
CAS# 60-00-4: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 60-00-4 is listed on Canada's DSL List. CAS# 60-00-4 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List.

This product has a WHMIS classification of D2B.
CAS# 60-00-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits

MSDS Creation Date: 6-1-02.
Revision Date: 5-20-11
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Robinson Consulting be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Robinson Consulting  has been advised of the possibility of such damages.