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Material Safety Data Sheet
Acid Titrant
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Section 1 - Chemical Product and Company Identification
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MSDS Name: Acid Titrant Synonyms: Company Identification: Robinson Consulting 609 8th ave South Sioux City NE. 68776 For information, call: 402.494.8250 or email TFRemily@aol.com
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Section 2 - Composition, Information on Ingredients
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CAS#
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Chemical Name
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Percent
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EINECS/ELINCS
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497-19-8
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Sodium carbonate
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0.10-20
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207-838-8
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7732-18-5
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Water
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balance
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231-791-2
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balance
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Water
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balance
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231-791-2
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231-792-2
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Water
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balance
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231-791-2
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Hazard Symbols: C Risk Phrases: 34
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless. Caution! May cause severe eye irritation and possible injury. May cause severe respiratory and digestive tract irritation with possible burns. Target Organs: None known.
Potential Health Effects Eye: May cause alkali burns, conjunctivial edema, corneal destruction, opacification, blurred vision, possible permanent damage. Skin: Alkali penetration, time and concentration dependant, can produce mild irritation to burns, ulceration. Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. If death does not occur in 24hr., victim improvement (2-4days) changes with sudden onset abdominal pain, rigidity, hypotension, possible gastric/esophageal perforation with corrosive damage to upper gastro-intestinal tract. Inhalation: May cause irritation and delayed pulmonary edema. Chronic: Repeated inhalation may cause perforation of the nasal septum. May cause dermatitis and conjunctivitis. May cause blurred vision and corneal damage.
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Section 4 - First Aid Measures
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Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid at once. Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes. Ingestion: Induce vomiting (touch finger to back of throat) keeping head lower than hips (prevent aspiration into lungs). Give conscious non-convulsive victim large quantities of water to dilute the alkali. Inhalation: Give artificial respiration if necessary. Get medical aid. Keep victim warm, at rest. Move victim to fresh air. Notes to Physician: Treat symptomatically and supportively.
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Section 5 - Firefighting Measures
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General Information: Negligible fire and explosion hazard when exposed to heat or flame. Move container if possible, avoid breathing vapors or dust. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal.
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Section 7 - Handling and Storage
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Handling: Wash thoroughly after handling. Avoid breathing dust, vapor, mist, or gas. Storage: Store capped at room temperature. Protect from heat and incompatibles.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls: Provide local exhaust or general dilution ventilation. Exposure Limits
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Chemical Name
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ACGIH
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NIOSH
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OSHA - Final PELs
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Sodium carbonate
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none listed
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none listed
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none listed
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Water
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none listed
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none listed
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none listed
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none listed
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none listed
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none listed
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OSHA Vacated PELs: Sodium carbonate: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Do not wear contact lenses when working with chemicals. An eye wash fountain should be available in the immediate work area. Wear splash-proof safety goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Not required for normal use. Firefighting-- any self-contained breathing apparatus with full facepiece operated in pressure-demand mode. High levels - use dust, mist, fume respirators.
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Section 9 - Physical and Chemical Properties
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Physical State: Clear liquid Appearance: colorless Odor: odorless pH: alkaline Vapor Pressure: 14mm Hg @20 deg C Vapor Density: 0.7 (H2O=1) Evaporation Rate:< ether Viscosity: Not available. Boiling Point: 212 deg F Freezing/Melting Point:32 deg F Decomposition Temperature:Not available. Autoignition Temperature: Not available. Flash Point: Not available. NFPA Rating: Not published. Explosion Limits, Lower:Not available. Upper: Not available. Solubility: Soluble. Specific Gravity/Density:1.0 Molecular Formula:Not available. Molecular Weight:Not available.
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Section 10 - Stability and Reactivity
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Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, corrosive to zinc. Prolonged exposure to air. Incompatibilities with Other Materials: Acids, aluminum, phosphorus pentoxide, fluorine, lithium. Hazardous Decomposition Products: Acrid smoke and fumes. Hazardous Polymerization: Has not been reported
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Section 11 - Toxicological Information
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RTECS#: CAS# 497-19-8 unlisted.
CAS# 7732-18-5 ZC0110000 LD50/LC50: CAS# 497-19-8: Inhalation, mouse: LC50 =1200 mg/m3/2H; Inhalation, rat: LC50 =2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral, rat: LD50 = 4090 mg/kg;<BR.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg;<BR.
Carcinogenicity: CAS# 497-19-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: Sodium carbonate is a severe eye, skin, and mucous membrane irritant. Teratogenicity: No data available. Reproductive Effects: No data available. Neurotoxicity: No data available. Mutagenicity: No data available. Other Studies: No data available.
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Section 12 - Ecological Information
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Ecotoxicity: Fish: Carp: 180ppm (LC100); 24H; No data available. Environmental: No data available
Physical: Not expected to biodegrade or bioconcentrate. Other: For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT
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IATA
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RID/ADR
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IMO
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Canada TDG
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Shipping Name:
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Not regulated
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Hazard Class:
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UN Number:
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Packing Group:
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Section 15 - Regulatory Information
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US FEDERAL
TSCA CAS# 497-19-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA
Section 302 (RQ) Not listed Section 302 (TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS # 497-19-8: acute.
Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: Not listed OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R34 causes burns Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 497-19-8: 1 CAS# 7732-18-5: No information available. Canada CAS# 497-19-8 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. WHMIS: E CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. Exposure Limits
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Section 16 - Additional Information
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MSDS Creation Date: 6-1-02. Update 5-19-11
Revision Date: Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and Robinson Consulting assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application.
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