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Material Safety Data Sheet

Acid Titrant

Section 1 - Chemical Product and Company Identification

MSDS Name: Acid Titrant
 Synonyms:
Company Identification:

             Robinson Consulting
             609 8th ave
             South Sioux City NE. 68776
For information, call:
402.494.8250  or email TFRemily@aol.com
 

Section 2 - Composition, Information on Ingredients

CAS#

Chemical Name

Percent

EINECS/ELINCS

497-19-8

Sodium carbonate

0.10-20

207-838-8

7732-18-5

Water

balance

231-791-2

 

Water

 

balance

231-791-2

 

balance

Water

balance

231-791-2

 

231-792-2

Water

balance

231-791-2

 

 

 

 

 


Hazard Symbols:
C
Risk Phrases:
34

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless. Caution! May cause severe eye irritation and possible injury. May cause severe respiratory and digestive tract irritation with possible burns.
Target Organs: None known.


Potential Health Effects
Eye: May cause alkali burns, conjunctivial edema, corneal destruction, opacification, blurred vision, possible permanent damage.
Skin: Alkali penetration, time and concentration dependant, can produce mild irritation to burns, ulceration.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. If death does not occur in 24hr., victim improvement (2-4days) changes with sudden onset abdominal pain, rigidity, hypotension, possible gastric/esophageal perforation with corrosive damage to upper gastro-intestinal tract.
Inhalation: May cause irritation and delayed pulmonary edema.
Chronic: Repeated inhalation may cause perforation of the nasal septum. May cause dermatitis and conjunctivitis. May cause blurred vision and corneal damage.

Section 4 - First Aid Measures



Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until no evidence of chemical remains. Get medical aid at once.
Skin: Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion: Induce vomiting (touch finger to back of throat) keeping head lower than hips (prevent aspiration into lungs). Give conscious non-convulsive victim large quantities of water to dilute the alkali.
Inhalation: Give artificial respiration if necessary. Get medical aid. Keep victim warm, at rest. Move victim to fresh air.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Firefighting Measures



General Information: Negligible fire and explosion hazard when exposed to heat or flame. Move container if possible, avoid breathing vapors or dust.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Section 6 - Accidental Release Measures



General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spills with absorbent (vermiculite, sand, fuller's earth) and place in plastic bags for later disposal.

Section 7 - Handling and Storage



Handling: Wash thoroughly after handling. Avoid breathing dust, vapor, mist, or gas.
Storage: Store capped at room temperature. Protect from heat and incompatibles.

Section 8 - Exposure Controls, Personal Protection



Engineering Controls: Provide local exhaust or general dilution ventilation.
Exposure Limits

Chemical Name

ACGIH

NIOSH

OSHA - Final PELs

Sodium carbonate

none listed

none listed

none listed

Water

none listed

none listed

none listed

 

none listed

none listed

none listed

 

 

 

 


OSHA Vacated PELs: Sodium carbonate: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Do not wear contact lenses when working with chemicals. An eye wash fountain should be available in the immediate work area. Wear splash-proof safety goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Not required for normal use. Firefighting-- any self-contained breathing apparatus with full facepiece operated in pressure-demand mode. High levels - use dust, mist, fume respirators.

Section 9 - Physical and Chemical Properties



Physical State: Clear liquid
Appearance: colorless
Odor: odorless
pH: alkaline
Vapor Pressure: 14mm Hg @20 deg C
Vapor Density: 0.7 (H2O=1)
Evaporation Rate:< ether
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point:32 deg F
Decomposition Temperature:Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble.
Specific Gravity/Density:1.0
Molecular Formula:Not available.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity



Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, corrosive to zinc. Prolonged exposure to air.
Incompatibilities with Other Materials: Acids, aluminum, phosphorus pentoxide, fluorine, lithium.
Hazardous Decomposition Products: Acrid smoke and fumes.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information



RTECS#:
CAS# 497-19-8 unlisted.


CAS# 7732-18-5 ZC0110000
LD50/LC50:
CAS# 497-19-8:
Inhalation, mouse: LC50 =1200 mg/m3/2H;
Inhalation, rat: LC50 =2300 mg/m3/2H;
Oral, mouse: LD50 = 6600 mg/kg;
Oral, rat: LD50 = 4090 mg/kg;<BR.


CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;<BR.

Carcinogenicity:
CAS# 497-19-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.  CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: Sodium carbonate is a severe eye, skin, and mucous membrane irritant.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.

Section 12 - Ecological Information

Ecotoxicity: Fish: Carp: 180ppm (LC100); 24H; No data available.
Environmental: No data available

Physical: Not expected to biodegrade or bioconcentrate.
Other: For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."


 

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT

IATA

RID/ADR

IMO

Canada TDG

Shipping Name:

Not regulated

 

 

 

 

Hazard Class:

 

 

 

 

 

UN Number:

 

 

 

 

 

Packing Group:

 

 

 

 

 

Section 15 - Regulatory Information


US FEDERAL

TSCA
CAS# 497-19-8 is listed on the TSCA inventory.

CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)
Not listed
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 497-19-8: acute.

Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
Not listed
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:

R34 causes burns
Safety Phrases:

S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).

WGK (Water Danger/Protection)

CAS# 497-19-8: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 497-19-8 is listed on Canada's DSL List.  CAS# 7732-18-5 is listed on Canada's DSL List.
WHMIS: E
CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits

 

Section 16 - Additional Information


MSDS Creation Date: 6-1-02.  Update 5-19-11

Revision Date:
Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and Robinson Consulting assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application.

Robinson Consulting